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Beilstein J. Org. Chem. 2014, 10, 2071–2076, doi:10.3762/bjoc.10.215
Graphical Abstract
Scheme 1: C–H functionalization of P(O)R2 directed through a seven-membered cyclopalladium transition state.
Scheme 2: Synthesis of chiral and racemic substrates.
Figure 1: C–H functionalization of axially chiral phosphorus substrates. The yields are isolated yields and t...